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Cage effect (chemistry) : ウィキペディア英語版 | Cage effect
The cage effect in chemistry describes how properties of a molecule are affected by its surroundings. In a solvent a molecule is often more accurately described existing in a cage of solvent molecules, the so-called solvent cage. Reactions occur when a molecule occasionally "jumps out" and meets another molecule. Typical cage lifetime in a solvent cage is 10−11s. Other examples include how in a gas at low pressure a normally highly reactive and short lived molecule can be contained. Also, specific host-guest interactions occur in inclusion compounds.
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Cage effect」の詳細全文を読む
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